Methyl α-bromoacrylate

Cat.No ACM4519464-1

Basic Information Application Features And Benefits

CAS	4519-46-4
Catalog Number	ACM4519464-1
Molecular Weight	164.99
Canonical SMILES	COC(=O)C(Br)=C
InChI	1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3
InChI Key	HVJXPDPGPORYKY-UHFFFAOYSA-N
Boiling Point	70-75 °C/48 mmHg (lit.)
Density	1.556 g/mL at 25 °C (lit.)
Assay	95%
MDL Number	MFCD08276754
NACRES	NA.23
Packaging	Packaging 1 g in glass insert
PubChem ID	24881219
Quality Level	100
Storage Temperature	−20°C

Application Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.

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