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Diallyl carbonate

Cat.No ACM15022089-1

Basic Information Description Application Features And Benefits
CAS 15022-08-9
Catalog Number ACM15022089-1
Synonyms Allyl carbonate;Carbonic acid, di-2-propenyl ester;Carbonic acid, diallyl ester;carbonicacid,di-2-propenylester;DIALLYL CARBONATE;Carbonic acid diallyl;Carbonic acid O,O-diallyl ester;Diallyl carbonate 99%
Molecular Weight 142.15
Molecular Formula (H2C=CHCH2O)2CO
Canonical SMILES C=CCOC(=O)OCC=C
InChI 1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2
InChI Key JKJWYKGYGWOAHT-UHFFFAOYSA-N
Boiling Point 95-97 °C/60 mmHg (lit.)
Density 0.991 g/mL at 25 °C (lit.)
Assay 99%
EC Number 239-106-9
MDL Number MFCD00008645
NACRES NA.23
Packaging Packaging
5, 25 g in glass bottle
PubChem ID 24856852
Quality Level 100
Refractive Index n20/D 1.428 (lit.)
Storage Temperature 2-8°C
Description Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.
Application Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.
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